Biographical info

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Santiago graduated both from the University of Greenwich (UK) where he was awarded his BSc with Honour Degree in Applied Chemistry in 1992, and from the University of País Vasco (Spain, Licenciado in Chemical Science) in 1996. In 2001 he obtained his PhD from the University of Málaga (Spain). His PhD research on the applications of laser induced plasma spectrometry to industrial processes under advisement of J.J. Laserna involved industrial laser welding, fully-automated quality assurance of stainless steel and development of several portable and stand-off LIBS instruments. In this context, he was invited to the Bremen Institute of Applied Laser Science (BIAS, Bremen, Germany) to develop a sensor for laser welding of aluminum, a work which was awarded by the Scientific Committee at the 1st International Conference on Laser Induced Plasma Spectroscopy and Applications (Pisa, Italy).

During his post-doc research at the University of Málaga, he worked on the development and uses of LIBS for remote sensing. In collaboration with the Army Research Laboratory (Department of Defense, US) the feasibility of stand-off LIBS for the detection of energetic materials in the field was demonstrated for the first time in 2004. In a follow-on work, he collaborated with OOI (US) and APL (UK) in the design and construction of five stand-off LIBS instruments for the ARL, and two more for the University of Málaga and Indra Sistemas (Spain).

In 2006, he joined efforts with Martin Richardson and moved to the University of Central Florida (US) to take a faculty position at CREOL as a Senior Scientist. He was responsible for a program on fundamental laser spectroscopy funded by the ARO (MURI) and put the foundations for the Laser Spectroscopy and Sensing Lab and the Laser Ignition Facility at the then-newborn Townes Laser Institute.

In 2009 he returned to the University of Málaga where he joined José Ramos-Barrado’s Group at the Department of Applied Physics I and was appointed as a Ramón y Cajal Research Scientist between 2010 and 2016. From May 2016 he is an associate professor. Since his return to Spain he has started a new lab and his research interests include the generation of nanostructures from laser-induced plasmas of precursor microdroplets, the use of plasma lenses for surface nanopatterning and the characterization of complex single and multilayered PV materials.

Education

BSc (Honours degree) Applied Chemistry, University of Greenwich (UK), 1992
Licenciado en Ciencias Químicas, University of País Vasco (Spain), 1996
Laser Engineer, Technischen Universität Wien (Austria), 1998
PhD Chemistry, University of Málaga (Spain), 2001

Appointments

1994 – 1998 Research Scientist University of Málaga
      1998 Research Scientist, BIAS – Uni Bremen
1999 – 2001 PhD, University of Málaga
2001 – 2006 Post-doc, University of Málaga
2006 – 2008 Senior Scientist, TLI/CREOL, University of Central Florida
      2008 Senior Scientist, Applied Photonics Ltd
2009 – 2010 Laboratory technician, University of Málaga
2010 – 2016 Ramón y Cajal Senior Scientist, University of Málaga
2016 – Associate Professor, University of Málaga
Panel 1

Publications

  1. V. Orlando, M. Gabás, B. Galiana, P. Espinet-González, S. Palanco, N. Nuñez, M. Vázquez, K. Araki, C. Algora, Failure analysis on lattice matched GaInP/Ga(In)As/Ge commercial concentrator solar cells after temperature accelerated life tests, Progress in Photovoltaics: Research and Applications, vol. 25 pp. 97-112, 2017.
  2. M. Lopez-Escalante, M. Gabas, I. Garcia, E. Barrigon, I. Rey-Stolle, C. Algora, S. Palanco, J. Ramos-Barrado, Differences between GaAs/GaInP and GaAs/AlInP interfaces grown by movpe revealed by depth profiling and angle-resolved X-ray photoelectron spectroscopies, Applied Surface Science, vol. 360, pp. 477-484, 2016.
  3. E. Ochoa-Martínez, M. Gabás, L. Barrutia, A. Pesquera, A. Centeno, S. Palanco, A. Zurutuza, C. Algora, “Determination of refractive index and extinction coefficient of standard production CVD-graphene,” Nanoscale, vol. 7, pp. 1491-1500, 2015.
  4. S. Marino, S. Palanco, M. Gabás, R. Romero, and J. R. Ramos-Barrado, “Laser nano- and micro-structuring of silicon using a laser-induced plasma for beam conditioning,” Nanotechnology, vol. 26, no. 5, pp. 055303, 2015.
  5. S. Palanco, S. Marino, M. Gabás, R. Romero, and J. R. Ramos-Barrado, “Laser nano- and micro-structuring of silicon using a laser-induced plasma for beam conditioning,” ES2559327, 2014.
  6. S. Palanco, S. Marino, M. Gabás, L. Ayala, and J. R. Ramos-Barrado, “Tailored Synthesis of Nanostructures by Laser Irradiation of a Precursor Microdroplet Stream in Open-Air,” Nanoscale, vol. 7, pp. 492-499, 2015.
  7. S. Palanco, M. Gabás, L. Ayala, J. R. Ramos-Barrado, S. Bijani, and S. Marino, “Procedimiento y dispositivo para la producción de nanopartículas mediante irradiación láser de precursores líquidos de tamaño microscópico,” ES2431266, 2014.
  8. S. Palanco, S. Marino, M. Gabás, S. Bijani, L. Ayala, and J. R. Ramos-Barrado, “Particle formation and plasma radiative losses during laser ablation suitability of the Sedov-Taylor scaling,” Optics Express, vol. 22, no. 13, pp. 16552–16557, 2014.
  9. S. Palanco, S. Marino, M. Gabás, S. Bijani, L. Ayala, and J. R. Ramos-Barrado, “Micro-and nanoparticle generation during nanosecond laser ablation: Correlation between mass and optical emissions,” Optics Express, vol. 22, no. 4, pp. 3991–3999, 2014.
  10. P. Espinet-Gonzalez, R. Romero, V. Orlando, M. Gabas, N. Nunez, M. Vazquez, S. Palanco, S. Bijani, Y. Contreras, B. Galiana, C. Algora, and K. Araki, “Case study in failure analysis of accelerated life tests (ALT) on III-V commercial triple-junction concentrator solar cells,” presented at the Conference Record of the IEEE Photovoltaic Specialists Conference, 2013, pp. 1666–1671.
  11. S. Palanco, M. Gabás, L. Ayala, S. Bijani, E. Barrigón, C. Algora, I. Rey-Stolle, and J. R. Ramos-Barrado, “Open-atmosphere structural depth profiling of multilayer samples of photovoltaic interest using laser-induced plasma spectrometry,” presented at the Conference Record of the IEEE Photovoltaic Specialists Conference, 2012, pp. 432–436.
  12. E. Ochoa, M. Gabás, S. Bijani, S. Palanco, A. R. Landa-Cánovas, P. Herrero, F. Agulló-Rueda, P. Díaz-Carrasco, and J. R. Ramos-Barrado, “Highly conductive Ga-doped ZnO thin films deposited onto Si wafers: Interface characterization,” presented at the Conference Record of the IEEE Photovoltaic Specialists Conference, 2012, pp. 427–431.
  13. M. Gabás, S. Palanco, S. Bijani, E. Barrigón, C. Algora, I. Rey-Stolle, I. García, and J. R. Ramos-Barrado, “Analysis of the surface state of epi-ready Ge wafers,” Applied Surface Science, vol. 258, no. 20, pp. 8166–8170, 2012.
  14. M. Gabas, M. C. Lopez-Escalante, C. Algora, I. Rey-Stolle, B. Galiana, S. Palanco, and J. R. Ramos-Barrado, “ARXPS analysis of a GaAs/GaInP heterointerface with application in III-V multijunction solar cells,” presented at the Conference Record of the IEEE Photovoltaic Specialists Conference, 2012, pp. 385–389.
  15. M. Gabás, M. C. López-Escalante, C. Algora, I. Rey-Stolle, E. Barrigón, I. García, B. Galiana, S. Palanco, S. Bijani, and J. R. Ramos-Barrado, “XPS as characterization tool for PV: From the substrate to complete III-V multijunction solar cells,” presented at the Conference Record of the IEEE Photovoltaic Specialists Conference, 2011, pp. 000229–000233.
  16. M. Gabás, M. C. López-Escalante, C. Algora, I. Rey-Stolle, E. Barrigón, I. García, B. Galiana, S. Palanco, S. Bijani, and J. R. Ramos-Barrado, “XPS as characterization tool for PV: From the substrate to complete III-V multijunction solar cells,” presented at the Conference Record of the IEEE Photovoltaic Specialists Conference, 2011, pp. 001711–001715.
  17. M. Weidman, M. Baudelet, S. Palanco, M. Sigman, P. J. Dagdigian, and M. Richardson, “Nd:YAG-CO2 double-pulse laser induced breakdown spectroscopy of organic films,” Optics Express, vol. 18, no. 1, pp. 259–266, 2010.
  18. M. Weidman, S. Palanco, M. Baudelet, and M. C. Richardson, “Thermodynamic and spectroscopic properties of Nd:YAG-CO2 Double-Pulse Laser-Induced Iron Plasmas,” Spectrochimica Acta – Part B Atomic Spectroscopy, vol. 64, no. 10, pp. 961–967, 2009.
  19. E. D. McNaghten, A. M. Parkes, B. C. Griffiths, A. I. Whitehouse, and S. Palanco, “Detection of trace concentrations of helium and argon in gas mixtures by laser-induced breakdown spectroscopy,” Spectrochimica Acta – Part B Atomic Spectroscopy, vol. 64, no. 10, pp. 1111–1118, 2009.
  20. S. Palanco and M. Richardson, “Laser-induced breakdown spectroscopy and related stand-off detection technologies,” presented at the Biomedical Optics, BIOMED 2008, 2008.
  21. C. López-Moreno, S. Palanco, and J. J. Laserna, “Stand-off analysis of moving targets using laser-induced breakdown spectroscopy,” Journal of Analytical Atomic Spectrometry, vol. 22, no. 1, pp. 84–87, 2007.
  22. S. Palanco, C. López-Moreno, and J. J. Laserna, “Design, construction and assessment of a field-deployable laser-induced breakdown spectrometer for remote elemental sensing,” Spectrochimica Acta – Part B Atomic Spectroscopy, vol. 61, no. 1, pp. 88–95, 2006.
  23. C. López-Moreno, S. Palanco, J. J. Laserna, F. DeLucia Jr., A. W. Miziolek, J. Rose, R. A. Walters, and A. I. Whitehouse, “Test of a stand-off laser-induced breakdown spectroscopy sensor for the detection of explosive residues on solid surfaces,” Journal of Analytical Atomic Spectrometry, vol. 21, no. 1, pp. 55–60, 2006.
  24. S. Palanco, J. J. Laserna, and A. Alises, “Sistema portátil para análisis químico elemental basado en espectrometría de emisión de plasmas inducidos por láser,” ES2234373, 2005.
  25. C. López-Moreno, S. Palanco, and J. J. Laserna, “Quantitative analysis of samples at high temperature with remote laser-induced breakdown spectrometry using a room-temperature calibration plot,” Spectrochimica Acta – Part B Atomic Spectroscopy, vol. 60, no. 7–8, pp. 1034–1039, 2005.
  26. C. López-Moreno, S. Palanco, and J. J. Laserna, “Calibration transfer method for the quantitative analysis of high-temperature materials with stand-off laser-induced breakdown spectroscopy,” Journal of Analytical Atomic Spectrometry, vol. 20, no. 11, pp. 1275–1279, 2005.
  27. C. Lopez-Moreno, K. Amponsah-Manager, B. W. Smith, I. B. Gornushkin, N. Omenetto, S. Palanco, J. J. Laserna, and J. D. Winefordner, “Quantitative analysis of low-alloy steel by microchip laser induced breakdown spectroscopy,” Journal of Analytical Atomic Spectrometry, vol. 20, no. 6, pp. 552–556, 2005.
  28. J. Cuñat, S. Palanco, F. Carrasco, M. D. Simón, and J. J. Laserna, “Portable instrument and analytical method using laser-induced breakdown spectrometry for in situ characterization of speleothems in karstic caves,” Journal of Analytical Atomic Spectrometry, vol. 20, no. 4, pp. 295–300, 2005.
  29. S. Palanco and J. Laserna, “Remote sensing instrument for solid samples based on open-path atomic emission spectrometry,” Review of Scientific Instruments, vol. 75, no. 6, pp. 2068–2074, 2004.
  30. S. Palanco, S. Conesa, and J. J. Laserna, “Analytical control of liquid steel in an induction melting furnace using a remote laser induced plasma spectrometer,” Journal of Analytical Atomic Spectrometry, vol. 19, no. 4, pp. 462–467, 2004.
  31. C. López-Moreno, S. Palanco, and J. J. Laserna, “Remote laser-induced plasma spectrometry for elemental analysis of samples of environmental interest,” Journal of Analytical Atomic Spectrometry, vol. 19, no. 11, pp. 1479–1484, 2004.
  32. S. Conesa, S. Palanco, and J. J. Laserna, “Acoustic and optical emission during laser-induced plasma formation,” Spectrochimica Acta – Part B Atomic Spectroscopy, vol. 59, no. 9, pp. 1395–1401, 2004.
  33. J. M. Vadillo, P. L. García, S. Palanco, D. Romero, J. M. Baena, and J. J. Laserna, “Remote, real-time, on-line monitoring of high-temperature samples by noninvasive open-path laser plasma spectrometry,” Analytical and Bioanalytical Chemistry, vol. 375, no. 8, pp. 1144–1147, 2003.
  34. A. J. Ramírez Del Valle, S. Palanco, J. J. Laserna, and J. P. Cosp, “Solar cells laser cutting process. Microstructurals modifications study,” Boletin de la Sociedad Espanola de Ceramica y Vidrio, vol. 42, no. 3, pp. 151–155, 2003.
  35. S. Palanco, J. M. Vadillo, P. L. Garcia, and J. J. Laserna, “Open-path laser-induced plasma spectrometry for long-range elemental analysis,” presented at the Conference on Lasers and Electro-Optics Europe – Technical Digest, 2003, p. 476.
  36. S. Palanco and J. Laserna, “Spectral analysis of the acoustic emission of laser-produced plasmas,” Applied Optics, vol. 42, no. 30, pp. 6078–6084, 2003.
  37. S. Palanco, M. Klassen, J. Skupin, K. Hansen, E. Schubert, G. Sepold, and J. J. Laserna, “Spectroscopic monitoring during laser welding of aluminum alloys for weld defects diagnostics,” presented at the Conference on Lasers and Electro-Optics Europe – Technical Digest, 2003, p. 499.
  38. S. Palanco, A. Alises, J. Cuñat, J. Baena, and J. J. Laserna, “Development of a portable laser-induced plasma spectrometer with fully-automated operation and quantitative analysis capabilities,” Journal of Analytical Atomic Spectrometry, vol. 18, no. 8, pp. 933–938, 2003.
  39. S. Palanco, J. M. Baena, and J. J. Laserna, “Open-path laser-induced plasma spectrometry for remote analytical measurements on solid surfaces,” Spectrochimica Acta – Part B Atomic Spectroscopy, vol. 57, no. 3, pp. 591–599, 2002.
  40. S. Palanco, M. Klassen, J. Skupin, K. Hansen, E. Schubert, G. Sepold, and J. J. Laserna, “Spectroscopic diagnostics on CW-laser welding plasmas of aluminum alloys,” Spectrochimica Acta – Part B Atomic Spectroscopy, vol. 56, no. 6, pp. 651–659, 2001.
  41. C. C. Garcia, J. M. Vadillo, S. Palanco, J. Ruiz, and J. J. Laserna, “Comparative analysis of layered materials using laser-induced plasma spectrometry and laser-ionization time-of-flight mass spectrometry,” Spectrochimica Acta – Part B Atomic Spectroscopy, vol. 56, no. 6, pp. 923–931, 2001.
  42. S. Palanco and J. J. Laserna, “Full automation of a laser-induced breakdown spectrometer for quality assessment in the steel industry with sample handling, surface preparation and quantitative analysis capabilities,” Journal of analytical atomic spectrometry, vol. 15, no. 10, pp. 1321–1327, 2000.
  43. M. P. Mateo, S. Palanco, J. M. Vadillo, and J. J. Laserna, “Fast atomic mapping of heterogeneous surfaces using microline-imaging laser-induced breakdown spectrometry,” Applied Spectroscopy, vol. 54, no. 10, pp. 1429–1434, 2000.
  44. S. Palanco and J. J. Laserna, “Sensor para monitorización on-line y remota de procesos automatizados de soldadura con láser,” ES2121702, 1999.
  45. S. Palanco and J. J. Laserna, “Sensor para la protección de guías ópticas contra roturas por torsión,” ES2119678, 1999.
  46. S. Palanco and J. J. Laserna, “Sensor para la protección de guÍas ópticas contra roturas por flexión,” ES2119679, 1999.
  47. S. Palanco, L. M. Cabalin, D. Romero, and J. J. Laserna, “Infrared laser ablation and atomic emission spectrometry of stainless steel at high temperatures,” Journal of analytical atomic spectrometry, vol. 14, no. 12, pp. 1883–1887, 1999.
  48. J. M. Vadillo, C. C. García, S. Palanco, and J. J. Laserna, “Nanometric range depth-resolved analysis of coated-steels using laser-induced breakdown spectrometry with a 308 nm collimated beam,” Journal of Analytical Atomic Spectrometry, vol. 13, no. 8, pp. 793–797, 1998.
  49. J. M. Vadillo, S. Palanco, M. D. Romero, and J. J. Laserna, “Applications of laser-induced breakdown spectrometry (LIBS) in surface analysis,” Fresenius’ journal of analytical chemistry, vol. 355, no. 7–8, pp. 909–912, 1996.
Panel 2

Presentations

2008-2018

  1. Open-atmosphere laser nanostructuring of silicon using a laser-induced plasma lens. Imaginenano 2018. Bilbao, Spain. 13/03/2018-15/03/2018. Palanco, S. Marino, M. Gabás, R. Romero, J.R. Ramos-Barrado.
  2. Influence of Graphene cleanliness on its optical properties. Graphene Week 2015. Manchester, UK. 22/06/2015-26/06/2015. A. Centeno, E. Ochoa-Martínez, M. Gabás, L. Barrutia, A. Pesquera, S. Palanco, A. Zurutuza, C. Algora.
  3. New generation architectures in III‐V multijunction solar cells for efficiencies of 50%. 10TH Spanish Conference on Electron Devices (CDE2015). Aranjuez, Spain. 11/02/2015-13/02/2015. C. Algora, I. Rey-Stolle, E. Barrigón, I. García, M. Vázquez, N. Núñez, R. Peña, P. Espinet, M. Ochoa, L. Ayllón, L. Barrutia, V. Orlando, H. Pengyun, M. Gabás, S. Palanco, C. Ballesteros, B. Galiana.
  4. Production of nanostructures in open air using nanosecond laser irradiation of precursor microdroplets. Nanotech Italy 2014. Venecia, 26/11/2014-28/11/2014. S. Palanco, S. Marino, M. Gabás, F. Martín, J.R. Ramos-Barrado.
  5. Case study in failure analysis of accelerated life tests (ALT) On III-V commercial triple-junction concentrator solar cells. PVSC – Photovoltaics Specialists Conference. Tampa, US. 16/06/2013-21/06/2013. P. Espinet-González, R. Romero, V. Orlando, M. Gabás, N. Núñez, M. Vázquez, S. Palanco, S. Bijani, Contreras, B. Galiana, C. Algora, K. Araki.
  6. Interface characterization of highly conductive Ga-doped ZnO thin films deposited onto Si wafers. 4TH International symposium on transparent conductive materials. Hersonissos, Kriti, Grecia. 21/10/2012-26/10/2012. M. Gabás, S. Palanco, E. Ochoa, S. Bijani, L. Ayala, J.L. Costa-Krämer, A.R. Landa-Canovas, P. Herrero, F. Agulló-Rueda, P. Diaz-Carrasco, J.R. Ramos-Barrado.
  7. ARXPS analysis of a GaAs/GaInP heterointerface with application in III-V multijunction solar cells. PVSC – Photovoltaics Specialists Conference. Austin, US. 03/06/2012-08/06/2012. M. Gabás, M.C. López-Escalante, C. Algora, I. Rey-Stolle, E. Barrigón, I. García, B. Galiana, S. Palanco, J.R. Ramos-Barrado.
  8. Highly ConductivE Ga-doped ZnO thin films deposited onto Si wafers: interface characterization. PVSC – Photovoltaics Specialists Conference. Austin, US. 03/06/2012-08/06/2012. E. Ochoa, M. Gabás, S. Bijani, S. Palanco, A.R. Landa-Canovas, P. Herrero, F. Agulló-Rueda, P. Diaz-Carrasco, J.R. Ramos-Barrado.
  9. Open-atmosphere structural depth profiling of multilayer samples of photovoltaic interest using laser-induced plasma spectrometry. Austin, US. 03/06/2012-08/06/2012. S. Palanco, M. Gabás, L. Ayala, S. Bijani, E. Barrigón, C. Algora, I. Rey-Stolle, J.R. Ramos-Barrado.
  10. Assessment of secondary neutral mass spectroscopy for the characterization of undoped and doped nanometric ZnO layers deposited on Si solar cells. NANOSMAT – 6TH International Conference on Surfaces, Coatings and Nanostructured Materials. Krakow, Polonia. 17/10/2011-20/10/2011. S. Bijani, S. Palanco, M. Gabás, J.R. Ramos-Barrado.
  11. On the fundamentals and processes leading to nanoparticle generation during laser ablation. NANOSMAT – 6TH International Conference on Surfaces, Coatings and Nanostructured Materials. Krakow, Polonia. 17/10/2011-20/10/2011. S. Palanco, M. Weidman, K. Lim, M. Baudelet, M.C. Richardson, S. Bijani, M. Gabás, J.R. Ramos-Barrado.
  12. Correlation between spectral emission and nanoparticle generation during nano- and femtosecond laser-induced breakdown. NASLIBS – North American Symposium on Laser Induced Breakdown Spectroscopy. Clearwater, FL, US. 18/07/2011-20/07/2011. S. Palanco, M. Baudelet, M. Weidman, M.C. Richardson, J.R. Ramos-Barrado.
  13. Comparison of the interfaces of ZnO, Ga:ZnO (2%) and Al:ZnO (2%) thin films, and Si (100) SUBSTRATES studied by XPS, UPS and TEM. PVSC – Photovoltaics Specialists Conference. Seatle, WA, US. 19/06/2011-24/06/2011. M. Gabás, M.C. López-Escalante, C. Algora, I. Rey-Stolle, E. Barrigón, I. García, B. Galiana, S. Palanco, S. Bijani, J.R. Ramos-Barrado.
  14. XPS as characterization tool for PV: from the substrate to complete III-V multijunction solar cells. PVSC – Photovoltaics Specialists Conference. SEATLE, WA, US. 19/06/2011-24/06/2011. M. Gabás, M.C. López-Escalante, C. Algora, I. Rey-Stolle, E. Barrigón, I. García, B. Galiana, S. Palanco, S. Bijani, J.R. Ramos-Barrado.
  15. X-RAY photoelectron spectroscopy as a tool to characterise Ge wafers surfaces of III-V multijunction solar cells. Spanish conference on electron devices. Mallorca, Spain. 09/06/2011-11/06/2011. M. Gabás, S. Palanco, S. Bijani, E. Barrigón, I. Rey-Stolle, C. Algora, J.R. Ramos-Barrado.
  16. Interface electronic structure of sputtering deposited undoped and doped ZnO thin films on a commercial Cz-Si solar cell substrate. CIMTEC 2010. Montecatini, Italia. 2010. M. Gabás, P. Díaz-Carrasco, S. Bijani, S. Palanco, P. Herrero, F. Agulló-Rueda, A.R. Landa-Cánovas, J.R. Ramos-Barrado.
  17. Thermodynamic properties of a Nd:YAG-CO2 double pulse laser-induced plasma and its applications under stand-off conditions. LACSEA 2008. St Petersburg, FL, US. 2008. M. Weidman, S. Palanco, M.C. Richardson.
  18. Detection of trace concentrations of helium and argon in gas mixtures by laser induced breakdown spectroscopy. 5th International conference on laser-induced breakdown spectroscopy, Berlin, Germany. 2008. E.D. Mcnaghten, A.M Parkes, B.C. Griffiths, A.I. Whitehouse, S. Palanco.
  19. Thermodynamic properties of Nd:YAG-CO2 double-pulse laser-induced plasma: applications under stand-off conditions. 5th International conference on laser-induced breakdown spectroscopy. Berlin, Germany. M. Weidman, S. Palanco, M. Baudelet, M. Sigman, M.C. Richardson.
Panel 3

Contact

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Departamento de Física Aplicada I
Facultad de Ciencias
Universidad de Málaga
Campus de Teatinos, s/n
29071 Málaga, Spain

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Unidad de Nanotecnología – The Nanotech Unit
Universidad de Málaga
Severo Ochoa 34
29590 Campanillas, Spain